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dc.contributor.authorŠícha, Václav
dc.contributor.authorFarràs, Pau
dc.contributor.authorŠtíbr, Bohumil
dc.contributor.authorTeixidor, Francesc
dc.contributor.authorGrüner, Bohumir
dc.contributor.authorViñas, Clara
dc.date.accessioned2016-08-15T10:31:12Z
dc.date.available2016-08-15T10:31:12Z
dc.date.issued2009-11-20
dc.identifier.citationŠícha, Václav, Farràs, Pau, Štíbr, Bohumil, Teixidor, Francesc, Grüner, Bohumír, & Viñas, Clara. (2009). Syntheses of C-substituted icosahedral dicarbaboranes bearing the 8-dioxane-cobalt bisdicarbollide moiety. Journal of Organometallic Chemistry, 694(11), 1599-1601. doi: http://dx.doi.org/10.1016/j.jorganchem.2008.10.059en_IE
dc.identifier.urihttp://hdl.handle.net/10379/5969
dc.description.abstractThe treatment of 1,2-, 1,7- and 1,12-carbaborane lithiated isomers with [3,3′-Co-8-(CH2CH2O)2-(1,2-C2B9H10)-(1′,2′-C2B9H11)] (1) at molar ratios 1:1 or 1:2 at room temperature in THF leads generally to the formation of a series of orange double-cluster mono and dianions. These were characterized by NMR and MS methods as [1′′-X-1′′,2′′-closo-C2B10H11]−, [2]−; [1′′-X-1′′,7′′-closo-C2B10H11]−, [3]− and [1′′-X-1′′,12′′-closo-C2B10H11], [4]− for the monoanions, whereas [1′′,2′′-X2-1′′,2′′-closo-C2B10H10]2−, [2]2−; [1′′,7′′-X2-1′′,7′′-closo-C2B10H10]2−, [3]2−; and [1′′,12′′-X2-1′′,12′′-closo-C2B10H10]2−, [4]2− for the dianions (where X = 3,3′-Co-8-(CH2CH2O)2-(1,2-C2B9H10)-1′,2′-(C2B9H11)). Moreover, these borane-cage subunits can be easily modified via attaching variable substituents onto cage carbon and boron vertices, which makes these compounds structurally flexible potential candidates for BNCT of cancer and HIV-PR inhibition.en_IE
dc.description.sponsorshipMinistry of Education of the Czech Republic (Project LC523), Research Plan AV0Z40320502 from AS CR, MEC (Grant MAT2006-05339), CSIC (I3P grant to P.F.) and the Generalitat de Catalunya 2005/SGR/00709en_IE
dc.formatapplication/pdfen_IE
dc.language.isoenen_IE
dc.publisherElsevieren_IE
dc.relation.ispartofJournal Of Organometallic Chemistryen
dc.subjectChemistryen_IE
dc.subjectCarboraneen_IE
dc.subjectMetallacarboranesen_IE
dc.subjectRing-openingen_IE
dc.subjectBNCTen_IE
dc.subjectPolyanionen_IE
dc.titleSyntheses of C-substituted icosahedral dicarbaboranes bearing the 8-dioxane-cobalt bisdicarbollide moietyen_IE
dc.typeArticleen_IE
dc.date.updated2016-08-10T17:00:40Z
dc.identifier.doi10.1016/j.jorganchem.2008.10.059
dc.local.publishedsourcehttp:/dx.doi.org/ 10.1016/j.jorganchem.2008.10.059en_IE
dc.description.peer-reviewedpeer-reviewed
dc.contributor.funder|~|
dc.internal.rssid9451819
dc.local.contactPau Farras. Email: pau.farrascosta@nuigalway.ie
dc.local.copyrightcheckedNo
dc.local.versionPUBLISHED
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